Processes and Balances

Separation Processes

13 min · 2 worked examplesFree

Getting the product out of the mixture, which is usually most of the plant and most of the energy.

After this lesson you can

  • Explain what distillation exploits
  • Match a separation method to the difference available
  • Say why separation usually costs more than the reaction

Distillation

Distillation separates liquids by boiling point. Heat the mixture and the vapour is richer in the more volatile component; condense it and you have separated a little.

A single stage rarely separates enough, so a column stacks many stages vertically. Vapour rises and liquid falls, contacting at each tray, and each contact improves the separation slightly. More trays means a purer product.

Reflux, returning some of the condensed overhead product to the top of the column, is what makes high purity possible, and it is expensive: everything refluxed must be boiled again.

Distillation is reckoned to account for a large share of all industrial separation energy, which is a direct consequence of the latent heat figure from the energy balance lesson.

In the full lesson

  1. Distillation
  2. Other separations
  3. Why separation dominates the cost

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